Open Access

The Effect Of Boron Compounds The Pore Formation And Surface Area Of Activated Carbon Obtained From Pistachio Shell

1 Harran University, Hilvan Vocational School, Program of Occupational Health and Safety, Sanliurfa

Abstract

It was reported the effect of boron compounds to the pore formation and surface area of active carbon (AC) obtained from the shell of pistachio. They were activated by using two different methods and five different compound. These methods and compounds were washing/waiting with hydrochloride (HCl) as acid solution or sodium hydroxide (NaOH) as base solution and waiting in boron compounds solution such as borax, boric acid and ammonium biborate. Shells were carbonized in high temperature furnace 900oC, 45 minute under CO2 washed H2O atmosphere. Obtained results were compared with untreated shells, only carbonized. The shells have 2.086cc/g DR pore volume, 1518m2/g of BET surface area, and 5865,632m2/g of micropore surface area for waiting in %10 ammonium biborate solution. The pore width as radius of obtained ACs and adsorption energy were 18,932Ao and 6,867kJ/mol for waiting in %10 ammonium biborate solution (ABB-PS). It was found that ABB-PS have higher micropore surface area, higher pore volume and lower adsorption energy. It was concluded that the pore structure and BET surface area of AC obtained from pistachio shell were developed by treating with boron compounds by compared of other compound in same conditions.

Keywords

How to Cite

DOLAS, H. (2022). The Effect Of Boron Compounds The Pore Formation And Surface Area Of Activated Carbon Obtained From Pistachio Shell. MAS Journal of Applied Sciences, 7(3), 657–669. https://doi.org/10.5281/zenodo.6798954

References

📄 Adekunle, M. A., Farid, N. A. 2015. Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: a review, renewable and sustainable energy reviews, 52: 1282-93.
📄 Barrett, E. P., Joyner, L. C., Halenda, P. H. 1951. The determination of pore volume and area distributions in porous substances. I. computations from nitrogen isotherms. J. Am. Chem. Soc. 73: 373-380.
📄 Carlos, J., Moreno, P., Giraldo, L. 2021. Heavy metal ions adsorption from wastewater using activated carbon from orange peel”, journal of chemistry, vol. 9, article ID: 383742, 12 pages.
📄 Carrott, P.J.M., Nabais, J.M.V., Ribeiro Carrott, M.M.L., Pajares, J.A., 2001. Preparation of activated carbon fibres from acrylic textile fibres, carbon, 39(10): 1543-55.
📄 Dolas, H., Sahin, O., Saka, C., Demir, H. 2011. A new method on producing high surface area activated carbon: The effect of salt on the surface aarea and the pore size distribution of activated carbon prepared from pistachio shell, Chemical Engineering Journal, 166: 191-197.